Revisions for RIP-ARCHAEOGEOCHEM

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07/21/2026 - 10:47 by illyria

Current revision
07/14/2026 - 11:12 by illyria

07/14/2026 - 10:38 by illyria

07/14/2026 - 09:47 by illyria

07/14/2026 - 09:39 by illyria

07/14/2026 - 09:39 by Filip Hájek

07/09/2026 - 09:07 by Filip Hájek

07/09/2026 - 09:07 by Filip Hájek

07/08/2026 - 16:42 by Mgr. Jan Fišer

07/04/2026 - 18:00 by Mgr. Jan Fišer

07/04/2026 - 17:50 by Mgr. Jan Fišer

Dataset Preview

Name
README_rip_archaeogeochem.csv
Soubor
README_rip_archaeogeochem.csv
README – RIP-ARCHAEOGEOCHEM – Dataset description
1. Dataset overview
RIP-ARCHAEOGEOCHEM (ver. 1.0.0)
An archaeogeochemical landscape dataset from the Mount Říp region, Czech Republic
This dataset was created by the Geoarchaeological Lab of the Centre for Field Archaeology, University of Hradec Kralove, as part of the project Long-term Land Use Dynamics within the Areas of Prehistoric Ritual Places (GACR Grant No. 25-15795K), funded by the Czech Science Foundation. It contains topsoil geochemical data collected in the Mount Říp region, Czech Republic, to support the investigation of archaeogeochemical signatures and long-term patterns of anthropogenic soil enrichment across the landscape. The dataset contains 1,291 topsoil samples, including elemental concentrations obtained by portable X-ray fluorescence spectroscopy (pXRF), together with metadata describing field sampling, laboratory processing, and the spatial location of each sample.
Author, orcid id:
Jan Fišer, 0000-0002-2295-4134
Petr Krištuf, 0000-0001-6389-6316
Jan Plíšek, 0009-0005-2454-2853
Jan Horák, 0000-0001-5589-7124
Contributor, orcid id:
Irena Supuková, 0009-0001-4232-9619
Nikola Rybenská, 0009-0005-6493-507X
Institutions:
University of Hradec Kralove
University of West Bohemia in Pilsen
Field sampling was carried out in March 2025 and April 2025. Laboratory analysis were taken between May 2025 and February 2026.
2. Dataset structure
2.1 Files included
readme_rip_archaeogeochem.txt
data_v1.0.0_rip_archaeogeochem.csv
2.2 Column description
Envi_id – Unique laboratory sample identifier.
Al_Concentration – Aluminium concentration measured by pXRF (ppm).
Si_Concentration – Silicon concentration measured by pXRF (ppm).
P_Concentration – Phosphorus concentration measured by pXRF (ppm).
K_Concentration – Potassium concentration measured by pXRF (ppm).
Ca_Concentration – Calcium concentration measured by pXRF (ppm).
Cr_Concentration – Chromium concentration measured by pXRF (ppm).
Mn_Concentration – Manganese concentration measured by pXRF (ppm).
Fe_Concentration – Iron concentration measured by pXRF (ppm).
Ni_Concentration – Nickel concentration measured by pXRF (ppm).
Zn_Concentration – Zinc concentration measured by pXRF (ppm).
Rb_Concentration – Rubidium concentration measured by pXRF (ppm).
Sr_Concentration – Strontium concentration measured by pXRF(ppm).
Y_Concentration – Yttrium concentration measured by pXRF(ppm).
Zr_Concentration – Zirconium concentration measured by pXRF (ppm).
Nb_Concentration – Niobium concentration measured by pXRF (ppm).
Ba_Concentration – Barium concentration measured by pXRF (ppm).
Pb_Concentration – Lead concentration measured by pXRF (ppm).
LE_Concentration – Instrument-specific light element (LE) parameter reported by the pXRF software.
Al_SigmaError – One-sigma (1σ) analytical uncertainty of the aluminium concentration measured by pXRF (ppm).
Si_SigmaError – One-sigma (1σ) analytical uncertainty of the silicon concentration measured by pXRF (ppm).
P_SigmaError – One-sigma (1σ) analytical uncertainty of the phosphorus concentration measured by pXRF (ppm).
K_SigmaError – One-sigma (1σ) analytical uncertainty of the potassium concentration measured by pXRF (ppm).
Ca_SigmaError – One-sigma (1σ) analytical uncertainty of the calcium concentration measured by pXRF (ppm).
Cr_SigmaError – One-sigma (1σ) analytical uncertainty of the chromium concentration measured by pXRF (ppm).
Mn_SigmaError – One-sigma (1σ) analytical uncertainty of the manganese concentration measured by pXRF (ppm).
Fe_SigmaError – One-sigma (1σ) analytical uncertainty of the iron concentration measured by pXRF (ppm).
Ni_SigmaError – One-sigma (1σ) analytical uncertainty of the nickel concentration measured by pXRF (ppm).
Zn_SigmaError – One-sigma (1σ) analytical uncertainty of the zinc concentration measured by pXRF (ppm).
Rb_SigmaError – One-sigma (1σ) analytical uncertainty of the rubidium concentration measured by pXRF (ppm).
Sr_SigmaError – One-sigma (1σ) analytical uncertainty of the strontium concentration measured by pXRF (ppm).
Y_SigmaError – One-sigma (1σ) analytical uncertainty of the yttrium concentration measured by pXRF (ppm).
Zr_SigmaError – One-sigma (1σ) analytical uncertainty of the zirconium concentration measured by pXRF (ppm).
Nb_SigmaError – One-sigma (1σ) analytical uncertainty of the niobium concentration measured by pXRF (ppm).
Ba_SigmaError – One-sigma (1σ) analytical uncertainty of the barium concentration measured by pXRF (ppm).
Pb_SigmaError – One-sigma (1σ) analytical uncertainty of the lead concentration measured by pXRF (ppm).
LE_SigmaError – One-sigma (1σ) analytical uncertainty associated with the instrument-specific light element (LE) parameter.
Field_date – Date of field sampling.
Field_cadaster – Cadastral area.
Homogenization_date – Date of sample homogenization.
xrf_analyse_date – Date of pXRF analysis.
xrf_analyse_device_serial_number – Instrument serial number.
xrf_analyse_real_time_1 – Acquisition time of first beam (s).
xrf_analyse_real_time_2 – Acquisition time of second beam (s).
Archaeological_category – Archaeological classification of sampling location.
coordinate_X – X coordinate (EPSG:5514).
coordinate_Y – Y coordinate (EPSG:5514).
2.3 Notes
Envi_id – Laboratory-assigned unique sample identifier. The identifier is unique within the Geochemical Laboratory (CETA).
LE_Concentration – Instrument-specific light element (LE) parameter reported by the pXRF software. This parameter does not represent the concentration of an individual chemical element.
LE_SigmaError – One-sigma (1σ) analytical uncertainty associated with the instrument-specific LE parameter.
3. Sampling methodology
Field sampling was carried out in March and April 2025 within a 10 × 10 km study area south-east of Roudnice nad Labem, Czech Republic, in the wider Mount Říp region. The sampling design combined two complementary strategies. First, a regular landscape-scale grid with 1 × 1 km spacing was used to capture broader regional geochemical patterns. Second, this grid-based sampling was supplemented by targeted sampling of archaeological sites divided into predefined categories, including settlement-related contexts, burial-related contexts, ambiguous feature concentrations, and background/non-site areas. At each selected archaeological location, a 50 × 50 m sampling square was established, within which 30 topsoil samples were collected randomly. Sampling locations were predefined and uploaded to the ArcGIS Field Maps mobile application, which was used to navigate to each sampling point. Sample locations were verified in the field using a smartphone with a minimum positional accuracy of 10 m, and all samples were collected from the surface ploughsoil (topsoil) horizon.
4. Laboratory workflow
Laboratory processing of the collected samples was carried out between May 2025 and February 2026. Samples were air-dried under laboratory conditions, manually pre-crushed and sieved to obtain the <2 mm fraction. Approximately 40–50 g of each sample was then homogenized using the laboratory's internal PM_9 protocol. Samples were milled for 3 minutes in a planetary ball mill using a mixture of 4 mm and 7 mm grinding balls with a total ball volume of 36 mL. Elemental concentrations were determined using an Olympus Vanta VCA portable energy-dispersive X-ray fluorescence (ED-XRF) spectrometer (serial no. 801404) operating in GeoChem-REE-Extra mode. Each sample was analysed using dual-beam irradiation (50 kV for 30 s and 10 kV for 30 s) and measured in triplicate. The reported elemental concentrations represent the arithmetic mean of the three measurements. Concentrations below the instrument's limit of detection were replaced by one-half of the minimum detected concentration for the respective element. Elemental concentrations are expressed in parts per million (ppm).
6. Coordinate reference system
S-JTSK / Krovak East North
EPSG:5514
coordinate_X = Easting
coordinate_Y = Northing
7. Data quality
The pXRF instrument undergoes annual calibration and performance testing by BAS Rudice Ltd. (https://www.bas.cz/).
8. Citation
When using this dataset, please cite both the dataset and the associated publication(s), where applicable:
Fišer, J., Krištuf, P., Plíšek, J., Horák, J. (2026) RIP-ARCHAEOGEOCHEM. ArchaeoVault. DOI:
9. Licence
CC BY 4.0
10. Contact
Jan Fišer
Archaeogeochemical lab
Centre for Field Archaeology
University of Hradec Králové
e-mail: jan.fiser@uhk.cz
ORCID: 0000-0002-2295-4134
10. Version
Current version: 1.0.0
Release date: 2026-07-01
11. Version history
Version 1.0.0 (2026-07-01)
• Initial public release.
MIME type
text/csv
File size
9
Media Use
Original File
Has header
No
Separator
^
Is documentation
True